We report a recent experiment where the first hard x-ray beam line, X-ray Pump Probe (XPP) instrument using the SLAC National Accelerator Laboratory's Linac Coherent Light Source (LCLS) free electron laser, was used to heat thin foils to high energy densities ~ 10⁷ J/cm³. An intense 9 keV, 60 fs (FWHM) duration beam with energy of 2 - 4 mJ at the XPP beam line was focused using beryllium lenses to an irradiance approaching $10^{16}$ $Wcm^{-2}$. Targets of 0.5 - 3.5 μm thick foils of Ag and Cu were studied using a suite of diagnostics including Fourier Domain Interferometry, energy calorimetry and grating and crystal spectrometers. The experimental details and spectroscopic results from the campaign will be described. Preliminary results indicate that the target is heated relatively uniformly to a temperature lower than 20 eV.