The European XFEL is a high-repetition multi-user facility with nominal photon energy range covering almost 3 orders of magnitude: 250 eV - 25 keV. In this work we explore the possibility to extend the photon energy range of the facility up to 100 keV via combination of superconducting undulator technology, period doubling and harmonic lasing, thus allowing for excellent tunability. To this purpose, we propose a dedicated FEL line, discuss its overall concept and provide analytical and numerical estimations of its expected performance.